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RefNoEC/1993/12
LevelItem
TitleFriend, Richard Henry: certificate of election to the Royal Society
Date1989
DescriptionCitation typed
CitationDistinguished for his experimental study of the electronic properties of novel materials, principally organic materials, both semiconductors and metals, and inorganic materials with "low Dimensional" electronic structure, including layer structure transition metal dichalcogenides and cuprate superconductors. He established the pressure/temperature phase diagrams for transition metal dichalcogenides, showing conditions for CDW (Charge Density Wave) phases and superconducting phases in TaS2, band crossing transition in TiS2 intercalation of transition metal dichalcogenides with various Lewis bases (alkali metals, amines), and use of controlled charge transfer to the host layer to fine-tune electronic structure in order to establish conditions for CDW superlattice formation, and mechanisms for charge transport.
He has made a major contribution to understanding the conditions for metallic, superconducting, magnetic and insulating ground states in organic charge transfer salts. Established the pressure/temperature phase diagram for the incommensurate and commensurate Charge Density Wave phases of TTF-TCNQ. He made the first observations of de Haas van Alphen oscillations in magnetic susceptibility in an organic metal. He and his group has developed polymer processing techniques for conjugated polymers, and demonstrated non-linear electronic excitations through electrical and optical measurements. First construction of MOSFET (Metal Insulator Semiconductor Field Effect Transistor) with polyacetylene as active semiconductor, and demonstration of novel mechanism of operation, with novel behaviour and made the first construction of efficient, large area, polymeric semi-conductor LED's (Light Emitting Diodes), based on polyphenylene-vinylene.
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